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EPlSC'b??pNH%X2ȘXJ "nq'd<ʐŵLH{:C 0OE_Q$B?_9dA5> ضı-4ٍ,0Mi('2Z'TXdܐ#<A>ể(=ضijv?6o$ɥĊ?8<-t׼>gWgGU{jY9{Țٝ*˺OBije? !OYtHDzwZz(}P8PX)qc9wzJ|ۣ3@ko/Yc>~4wCC~GOA~('o!2G5rLV!/_ر򵓨]Nߪ_Xm[6yz:0L\NP:X選r MhfH% "4ڏi<ANQ: _Vvf{}_ꀅZĤGY A²M,.k6n+ h q[Gh7*"k-dmk9YgހƑΰ? />p3(8ś<~Q׶ŧ=+'v3> 3$d".$|t /Cj8mh\=xln0le&盦r&E‰2| +2 `@ȰϭڣD&\9 :EF CW@#(#^نB셌_9 bCRyhQ4lUL;%/+/Y)DZ[n d#^R6(*άuѷgvv cuqMPJ_@Ee1kס SY‚Lq 2AΚ% WmAż"0Bs p1ȵ3Iѹ /ֵWl/eFyĤsr BTp:X +zS|!-? p$=G=[J"Jh< @\=8WV2F]b;2<~[[,[q_b{諜 T O)WrjU AB Jcz<ǚ]X7f- nv ]5ğ_1WPČD]g:@E<2r̖M"j#,;g qH â^媈 PWA&:,ǵ嬅2Rv .C6Nt(F5s ,LM|et *M1q8dvANXBa n2e2*F Ȑm`C[}/ucL+@򈊆CVd#9OµJ1& endstream endobj 94 0 obj << /Length 54 /Filter [ /FlateDecode ] >> stream x+TP01335S0B#C=33K=C##cK=\}$Kc|@M  endstream endobj 95 0 obj << /Length 9901 >> stream q BT 3 Tr /FontHelvetica 9.0 Tf 1 0 0 1 103.2 431.0 Tm (The ) Tj 1 0 0 1 123.8 431.0 Tm (fluorescence ) Tj 1 0 0 1 182.4 431.0 Tm (excitation ) Tj 1 0 0 1 227.5 431.0 Tm (spectrum ) Tj 1 0 0 1 271.0 431.0 Tm (measured ) Tj 1 0 0 1 317.0 431.0 Tm (with ) Tj 1 0 0 1 338.2 431.0 Tm (a ) Tj 1 0 0 1 348.0 431.0 Tm (mixture ) Tj 1 0 0 1 384.0 431.0 Tm (of ) Tj 1 0 0 1 396.0 431.0 Tm (cis- ) Tj 1 0 0 1 414.2 431.0 Tm (and ) Tj 1 0 0 1 434.6 431.0 Tm (trans-hexatrienes ) Tj 1 0 0 1 515.8 431.0 Tm (is) Tj 1 0 0 1 71.0 421.0 Tm (shown ) Tj 1 0 0 1 102.0 421.0 Tm (in ) Tj 1 0 0 1 112.3 421.0 Tm (Fig. ) Tj 1 0 0 1 131.8 421.0 Tm (1. ) Tj 1 0 0 1 146.6 421.0 Tm (The ) Tj 1 0 0 1 166.8 421.0 Tm (positions ) Tj 1 0 0 1 207.8 421.0 Tm (and ) Tj 1 0 0 1 227.5 421.0 Tm (relative ) Tj 1 0 0 1 261.6 421.0 Tm (intensities ) Tj 1 0 0 1 307.2 421.0 Tm (of ) Tj 1 0 0 1 318.0 421.0 Tm (the ) Tj 1 0 0 1 334.6 421.0 Tm (peaks ) Tj 1 0 0 1 363.6 421.0 Tm (are ) Tj 1 0 0 1 380.4 421.0 Tm (given ) Tj 1 0 0 1 406.8 421.0 Tm (within ) Tj 1 0 0 1 435.1 421.0 Tm (the ) Tj 1 0 0 1 451.2 421.0 Tm (figure. ) Tj 1 0 0 1 486.2 421.0 Tm (Based ) Tj 1 0 0 1 516.5 421.0 Tm (on) Tj 1 0 0 1 70.8 410.2 Tm (the ) Tj 1 0 0 1 88.6 410.2 Tm (assignment ) Tj 1 0 0 1 140.4 410.2 Tm (of ) Tj 1 0 0 1 151.4 410.2 Tm (previously ) Tj 1 0 0 1 198.2 410.2 Tm (measured ) Tj 1 0 0 1 244.3 410.2 Tm (Resonance ) Tj 1 0 0 1 295.4 410.2 Tm (Enhanced ) Tj 1 0 0 1 341.3 410.2 Tm (Multiphoton ) Tj 1 0 0 1 394.3 410.2 Tm (Ionization ) Tj 1 0 0 1 439.9 410.2 Tm (\(REMPI\) ) Tj 1 0 0 1 479.5 410.2 Tm (spectrum ) Tj 1 0 0 1 522.5 410.2 Tm (by) Tj 1 0 0 1 71.0 397.4 Tm (Buma ) Tj 1 0 0 1 100.6 397.4 Tm (et ) Tj 1 0 0 1 110.6 397.4 Tm (a/.,? ) Tj 1 0 0 1 131.3 397.4 Tm (the ) Tj 1 0 0 1 147.6 397.4 Tm (spectrum ) Tj 1 0 0 1 190.1 397.4 Tm (in ) Tj 1 0 0 1 200.4 397.4 Tm (Fig. ) Tj 1 0 0 1 220.3 397.4 Tm (1 ) Tj 1 0 0 1 228.2 397.4 Tm (is ) Tj 1 0 0 1 238.6 397.4 Tm (assigned ) Tj 1 0 0 1 279.1 397.4 Tm (to ) Tj 1 0 0 1 290.4 397.4 Tm (the ) Tj 1 0 0 1 306.5 397.4 Tm (81 ) Tj 1 0 0 1 320.9 397.4 Tm (state ) Tj 1 0 0 1 344.9 397.4 Tm (of ) Tj 1 0 0 1 355.2 397.4 Tm (the ) Tj 1 0 0 1 372.5 397.4 Tm (cis-hexatriene. ) Tj 1 0 0 1 442.1 397.4 Tm (Even ) Tj 1 0 0 1 467.0 397.4 Tm (though ) Tj 1 0 0 1 500.2 397.4 Tm (the) Tj 1 0 0 1 70.8 385.7 Tm (concentration ) Tj 1 0 0 1 133.0 385.7 Tm (of ) Tj 1 0 0 1 144.2 385.7 Tm (the ) Tj 1 0 0 1 162.2 385.7 Tm (trans-isomer ) Tj 1 0 0 1 219.6 385.7 Tm (is ) Tj 1 0 0 1 230.9 385.7 Tm (at ) Tj 1 0 0 1 242.4 385.7 Tm (least ) Tj 1 0 0 1 265.2 385.7 Tm (as ) Tj 1 0 0 1 279.4 385.7 Tm (great ) Tj 1 0 0 1 303.8 385.7 Tm (as ) Tj 1 0 0 1 317.0 385.7 Tm (the ) Tj 1 0 0 1 335.5 385.7 Tm (cis-isomer, ) Tj 1 0 0 1 385.2 385.7 Tm (its ) Tj 1 0 0 1 398.9 385.7 Tm (spectrum ) Tj 1 0 0 1 442.6 385.7 Tm (could ) Tj 1 0 0 1 470.9 385.7 Tm (not ) Tj 1 0 0 1 487.4 385.7 Tm (be) Tj 1 0 0 1 70.1 373.7 Tm (observed. ) Tj 1 0 0 1 119.3 373.7 Tm (The ) Tj 1 0 0 1 138.7 373.7 Tm (origin ) Tj 1 0 0 1 165.8 373.7 Tm (region ) Tj 1 0 0 1 195.4 373.7 Tm (consists ) Tj 1 0 0 1 234.0 373.7 Tm (of ) Tj 1 0 0 1 244.8 373.7 Tm (two ) Tj 1 0 0 1 263.0 373.7 Tm (major ) Tj 1 0 0 1 289.9 373.7 Tm (peaks ) Tj 1 0 0 1 318.5 373.7 Tm (separated ) Tj 1 0 0 1 364.1 373.7 Tm (by ) Tj 1 0 0 1 377.5 373.7 Tm (-5.7 ) Tj 1 0 0 1 398.6 373.7 Tm (cm-1. ) Tj 1 0 0 1 429.8 373.7 Tm (This ) Tj 1 0 0 1 451.9 373.7 Tm (doublet ) Tj 1 0 0 1 486.5 373.7 Tm (shows) Tj 1 0 0 1 70.8 363.1 Tm (further ) Tj 1 0 0 1 102.7 363.1 Tm (s,tructure ) Tj 1 0 0 1 143.8 363.1 Tm (due ) Tj 1 0 0 1 163.9 363.1 Tm (to ) Tj 1 0 0 1 176.2 363.1 Tm (partially ) Tj 1 0 0 1 213.8 363.1 Tm (resolved ) Tj 1 0 0 1 254.4 363.1 Tm (rotational ) Tj 1 0 0 1 296.9 363.1 Tm (features. ) Tj 1 0 0 1 343.0 363.1 Tm (Changing ) Tj 1 0 0 1 388.1 363.1 Tm (the ) Tj 1 0 0 1 405.6 363.1 Tm (expansion ) Tj 1 0 0 1 453.8 363.1 Tm (conditions ) Tj 1 0 0 1 501.8 363.1 Tm (affects) Tj 1 0 0 1 70.6 352.6 Tm (the ) Tj 1 0 0 1 88.1 352.6 Tm (rotational ) Tj 1 0 0 1 130.6 352.6 Tm (structure, ) Tj 1 0 0 1 174.5 352.6 Tm (however, ) Tj 1 0 0 1 217.9 352.6 Tm (the ) Tj 1 0 0 1 235.4 352.6 Tm (relative ) Tj 1 0 0 1 270.2 352.6 Tm (integrated ) Tj 1 0 0 1 316.3 352.6 Tm (intensities ) Tj 1 0 0 1 363.1 352.6 Tm (of ) Tj 1 0 0 1 374.4 352.6 Tm (the ) Tj 1 0 0 1 391.7 352.6 Tm (two ) Tj 1 0 0 1 410.6 352.6 Tm (bands ) Tj 1 0 0 1 441.1 352.6 Tm (are ) Tj 1 0 0 1 459.8 352.6 Tm (not ) Tj 1 0 0 1 475.4 352.6 Tm (changed.) Tj 1 0 0 1 70.6 342.0 Tm (The ) Tj 1 0 0 1 91.2 342.0 Tm (rotational ) Tj 1 0 0 1 134.9 342.0 Tm (lineshapes ) Tj 1 0 0 1 185.0 342.0 Tm (of ) Tj 1 0 0 1 196.8 342.0 Tm (the ) Tj 1 0 0 1 214.1 342.0 Tm (origin ) Tj 1 0 0 1 242.2 342.0 Tm (bands ) Tj 1 0 0 1 272.2 342.0 Tm (are ) Tj 1 0 0 1 290.4 342.0 Tm (consistent ) Tj 1 0 0 1 336.7 342.0 Tm (with ) Tj 1 0 0 1 358.1 342.0 Tm (a ) Tj 1 0 0 1 367.2 342.0 Tm (predominantly ) Tj 1 0 0 1 432.0 342.0 Tm (parallel ) Tj 1 0 0 1 467.5 342.0 Tm (transition ) Tj 1 0 0 1 512.2 342.0 Tm (of) Tj 1 0 0 1 71.5 329.0 Tm (cis-hexatriene. ) Tj 1 0 0 1 140.9 329.0 Tm (The ) Tj 1 0 0 1 161.8 329.0 Tm (1A1 ) Tj 1 0 0 1 181.4 329.0 Tm (~ ) Tj 1 0 0 1 193.7 329.0 Tm (1A1 ) Tj 1 0 0 1 212.6 329.0 Tm (transition ) Tj 1 0 0 1 255.8 329.0 Tm (is ) Tj 1 0 0 1 266.2 329.0 Tm (allowed ) Tj 1 0 0 1 301.9 329.0 Tm (for ) Tj 1 0 0 1 317.3 329.0 Tm (a ) Tj 1 0 0 1 326.2 329.0 Tm (molecule ) Tj 1 0 0 1 367.9 329.0 Tm (with ) Tj 1 0 0 1 388.8 329.0 Tm (a ) Tj 1 0 0 1 398.9 329.0 Tm (C2v ) Tj 1 0 0 1 418.1 329.0 Tm (symmetry, ) Tj 1 0 0 1 467.3 329.0 Tm (however, ) Tj 1 0 0 1 511.4 329.0 Tm (a) Tj 1 0 0 1 70.3 317.0 Tm (perpendicular ) Tj 1 0 0 1 132.5 317.0 Tm (band ) Tj 1 0 0 1 157.7 317.0 Tm (is ) Tj 1 0 0 1 168.5 317.0 Tm (expected. ) Tj 1 0 0 1 218.2 317.0 Tm (This ) Tj 1 0 0 1 240.7 317.0 Tm (spectrum ) Tj 1 0 0 1 283.9 317.0 Tm (appears ) Tj 1 0 0 1 321.8 317.0 Tm (to ) Tj 1 0 0 1 333.6 317.0 Tm (derive ) Tj 1 0 0 1 364.3 317.0 Tm (its ) Tj 1 0 0 1 377.8 317.0 Tm (oscillator ) Tj 1 0 0 1 420.2 317.0 Tm (strength ) Tj 1 0 0 1 460.3 317.0 Tm (by ) Tj 1 0 0 1 474.7 317.0 Tm (intensity) Tj 1 0 0 1 70.3 306.5 Tm (borrowing ) Tj 1 0 0 1 115.9 306.5 Tm (from ) Tj 1 0 0 1 139.0 306.5 Tm (the ) Tj 1 0 0 1 157.0 306.5 Tm (82 ) Tj 1 0 0 1 171.1 306.5 Tm (~ ) Tj 1 0 0 1 183.6 306.5 Tm (80 ) Tj 1 0 0 1 197.3 306.5 Tm (transition. ) Tj 1 0 0 1 247.0 306.5 Tm (This ) Tj 1 0 0 1 269.0 306.5 Tm (is ) Tj 1 0 0 1 279.6 306.5 Tm (a ) Tj 1 0 0 1 288.5 306.5 Tm (common ) Tj 1 0 0 1 328.3 306.5 Tm (feature ) Tj 1 0 0 1 361.7 306.5 Tm (to ) Tj 1 0 0 1 373.4 306.5 Tm (all ) Tj 1 0 0 1 387.1 306.5 Tm (linear ) Tj 1 0 0 1 414.2 306.5 Tm (polyene ) Tj 1 0 0 1 452.2 306.5 Tm (spectra ) Tj 1 0 0 1 487.2 306.5 Tm (presented) Tj 1 0 0 1 70.3 293.3 Tm (here: ) Tj 1 0 0 1 100.1 293.3 Tm (the ) Tj 1 0 0 1 117.4 293.3 Tm (symmetry ) Tj 1 0 0 1 162.5 293.3 Tm (forbidden ) Tj 1 0 0 1 206.6 293.3 Tm (21 ) Tj 1 0 0 1 217.0 293.3 Tm (Ag ) Tj 1 0 0 1 232.6 293.3 Tm (~ ) Tj 1 0 0 1 244.3 293.3 Tm (11 ) Tj 1 0 0 1 254.4 293.3 Tm (Ag ) Tj 1 0 0 1 270.2 293.3 Tm (transition ) Tj 1 0 0 1 313.2 293.3 Tm (gains ) Tj 1 0 0 1 341.3 293.3 Tm (intensity ) Tj 1 0 0 1 380.6 293.3 Tm (by ) Tj 1 0 0 1 394.1 293.3 Tm (vibronic ) Tj 1 0 0 1 432.2 293.3 Tm (coupling ) Tj 1 0 0 1 472.6 293.3 Tm (between) Tj 1 0 0 1 70.6 279.4 Tm (11Bu ) Tj 1 0 0 1 95.5 279.4 Tm (and ) Tj 1 0 0 1 114.5 279.4 Tm (21 ) Tj 1 0 0 1 124.3 279.4 Tm (Ag ) Tj 1 0 0 1 138.7 279.4 Tm (states. ) Tj 1 0 0 1 174.2 279.4 Tm (Although ) Tj 1 0 0 1 215.5 279.4 Tm (the ) Tj 1 0 0 1 232.1 279.4 Tm (presence ) Tj 1 0 0 1 275.3 279.4 Tm (of ) Tj 1 0 0 1 286.1 279.4 Tm (a ) Tj 1 0 0 1 294.7 279.4 Tm (cis-linkage ) Tj 1 0 0 1 343.7 279.4 Tm (or ) Tj 1 0 0 1 356.2 279.4 Tm (asymmetric ) Tj 1 0 0 1 409.2 279.4 Tm (substitution ) Tj 1 0 0 1 463.0 279.4 Tm (by ) Tj 1 0 0 1 476.4 279.4 Tm (a ) Tj 1 0 0 1 485.8 279.4 Tm (methyl) Tj 1 0 0 1 70.1 267.6 Tm (group ) Tj 1 0 0 1 98.9 267.6 Tm (breaks ) Tj 1 0 0 1 131.8 267.6 Tm (the ) Tj 1 0 0 1 149.3 267.6 Tm (molecular ) Tj 1 0 0 1 194.4 267.6 Tm (symmetry, ) Tj 1 0 0 1 243.8 267.6 Tm (the ) Tj 1 0 0 1 261.8 267.6 Tm (dominant ) Tj 1 0 0 1 305.5 267.6 Tm (effect ) Tj 1 0 0 1 332.2 267.6 Tm (which ) Tj 1 0 0 1 361.0 267.6 Tm (determines ) Tj 1 0 0 1 413.0 267.6 Tm (the ) Tj 1 0 0 1 430.8 267.6 Tm (oscillator ) Tj 1 0 0 1 474.0 267.6 Tm (strength ) Tj 1 0 0 1 513.4 267.6 Tm (for) Tj 1 0 0 1 70.1 257.5 Tm (the ) Tj 1 0 0 1 86.9 257.5 Tm (81 ) Tj 1 0 0 1 101.5 257.5 Tm (~ ) Tj 1 0 0 1 114.5 257.5 Tm (80 ) Tj 1 0 0 1 127.7 257.5 Tm (spectra ) Tj 1 0 0 1 163.2 257.5 Tm (of ) Tj 1 0 0 1 174.7 257.5 Tm (linear ) Tj 1 0 0 1 201.8 257.5 Tm (polyenes ) Tj 1 0 0 1 244.3 257.5 Tm (is ) Tj 1 0 0 1 254.2 257.5 Tm (vibronic ) Tj 1 0 0 1 290.2 257.5 Tm (coupling. ) Tj 1 0 0 1 337.0 257.5 Tm (For ) Tj 1 0 0 1 355.2 257.5 Tm (that ) Tj 1 0 0 1 374.6 257.5 Tm (reason ) Tj 1 0 0 1 407.3 257.5 Tm (g ) Tj 1 0 0 1 416.6 257.5 Tm (and ) Tj 1 0 0 1 436.6 257.5 Tm (u ) Tj 1 0 0 1 445.7 257.5 Tm (symmetry ) Tj 1 0 0 1 491.3 257.5 Tm (labels ) Tj 1 0 0 1 520.1 257.5 Tm (will) Tj 1 0 0 1 70.1 246.0 Tm (be ) Tj 1 0 0 1 84.7 246.0 Tm (retained ) Tj 1 0 0 1 123.8 246.0 Tm (throughout ) Tj 1 0 0 1 172.6 246.0 Tm (this ) Tj 1 0 0 1 192.5 246.0 Tm (text, ) Tj 1 0 0 1 214.1 246.0 Tm (even ) Tj 1 0 0 1 238.6 246.0 Tm (though ) Tj 1 0 0 1 271.4 246.0 Tm (the ) Tj 1 0 0 1 289.2 246.0 Tm (labels ) Tj 1 0 0 1 318.0 246.0 Tm (may ) Tj 1 0 0 1 340.6 246.0 Tm (not ) Tj 1 0 0 1 357.6 246.0 Tm (apply ) Tj 1 0 0 1 383.8 246.0 Tm (strictly ) Tj 1 0 0 1 415.2 246.0 Tm (to ) Tj 1 0 0 1 427.7 246.0 Tm (individual ) Tj 1 0 0 1 471.6 246.0 Tm (molecules.) Tj ET Q endstream endobj 96 0 obj << /Type /XObject /Subtype /Image /Name /Ob96 /Width 1940 /Height 360 /BitsPerComponent 1 /Length 37220 /Filter [ /FlateDecode ] /ColorSpace /DeviceGray >> stream xAȶl4؃QS^xzP ]l˻\d޼c b\£go.10D6/ÿ ɬ*%uKF*$_'#NcKBc')%',zORVwWJsCQ40HNV5v#cdEVvyo!췓 MY5,rE)`K!=d]9{ JwHam܄(q(+s+H }BaZ yk6} )h F䩍"ʹ0]lʷnyיv rH`a{kZM}ɦurίM:mT *k=Y}RMW&C/'Jgȩ~ȋunF9?]7"Ǫ*ڐIr΃\|r 9P&y'{ 8'cdIx,+!'=rq+:^F= e3܆}&dPmREG !.Nݼa\"j 8"'MUv= +$#s/"t!K,$h+TD3>~_6 lRUE=쒲ywB~栓:JhG*0eS)W&*ϑr_ycKʌ[Y3u#sd͕u)gU:!+tZ..4/=QEnVb[rb DiM^-Y0";vL}|Zo2yM !W!ߥ.JZ +ry!؍I$]qu -U8J$ |oRNW.nLjjɺ𮚤M8e}^5 k!r}5MAi׶Z2~Zފ&]۳>ҀOʸ<2_Va򨝢5ߥY=q@NA. 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--]|rx9Pl$+' b uL:r+AˉxtI˵s %hABaHe`0!?6;e??7OzW"VeͭĶrhqwF_BQ endstream endobj 243 0 obj << /Length 11390 >> stream q BT 3 Tr /FontHelvetica 9.0 Tf 1 0 0 1 111.1 395.5 Tm (Decatetraene. ) Tj 1 0 0 1 181.7 395.5 Tm (The ) Tj 1 0 0 1 202.3 395.5 Tm (measured ) Tj 1 0 0 1 248.9 395.5 Tm (fluorescence ) Tj 1 0 0 1 306.7 395.5 Tm (excitation ) Tj 1 0 0 1 350.9 395.5 Tm (spectra ) Tj 1 0 0 1 386.2 395.5 Tm (of ) Tj 1 0 0 1 397.5 395.5 Tm (the ) Tj 1 0 0 1 414.7 395.5 Tm (S1 ) Tj 1 0 0 1 429.4 395.5 Tm (\(- ) Tj 1 0 0 1 441.4 395.5 Tm (So ) Tj 1 0 0 1 456.3 395.5 Tm (transition ) Tj 1 0 0 1 499.2 395.5 Tm (and ) Tj 1 0 0 1 518.7 395.5 Tm (the) Tj 1 0 0 1 79.0 384.0 Tm (fluorescence ) Tj 1 0 0 1 135.4 384.0 Tm (decay ) Tj 1 0 0 1 163.9 384.0 Tm (rates ) Tj 1 0 0 1 187.7 384.0 Tm (for ) Tj 1 0 0 1 203.3 384.0 Tm (DT ) Tj 1 0 0 1 217.9 384.0 Tm (are ) Tj 1 0 0 1 234.7 384.0 Tm (shown ) Tj 1 0 0 1 265.2 384.0 Tm (in ) Tj 1 0 0 1 275.1 384.0 Tm (Fig. ) Tj 1 0 0 1 293.1 384.0 Tm (3a. ) Tj 1 0 0 1 313.0 384.0 Tm (The ) Tj 1 0 0 1 331.9 384.0 Tm (origin ) Tj 1 0 0 1 358.8 384.0 Tm (of ) Tj 1 0 0 1 369.1 384.0 Tm (the ) Tj 1 0 0 1 386.4 384.0 Tm (DT ) Tj 1 0 0 1 400.8 384.0 Tm (S1 ) Tj 1 0 0 1 415.2 384.0 Tm (\(- ) Tj 1 0 0 1 426.7 384.0 Tm (So ) Tj 1 0 0 1 440.7 384.0 Tm (spectrum ) Tj 1 0 0 1 483.1 384.0 Tm (has ) Tj 1 0 0 1 502.6 384.0 Tm (been) Tj 1 0 0 1 79.2 370.8 Tm (assigned ) Tj 1 0 0 1 121.0 370.8 Tm (to ) Tj 1 0 0 1 132.5 370.8 Tm (the ) Tj 1 0 0 1 149.8 370.8 Tm (intense ) Tj 1 0 0 1 185.1 370.8 Tm (triplet ) Tj 1 0 0 1 212.7 370.8 Tm (of ) Tj 1 0 0 1 223.7 370.8 Tm (peaks ) Tj 1 0 0 1 253.0 370.8 Tm (with ) Tj 1 0 0 1 273.6 370.8 Tm (the ) Tj 1 0 0 1 290.7 370.8 Tm (center ) Tj 1 0 0 1 321.4 370.8 Tm (of ) Tj 1 0 0 1 332.4 370.8 Tm (the ) Tj 1 0 0 1 350.4 370.8 Tm (lowest ) Tj 1 0 0 1 380.2 370.8 Tm (energy ) Tj 1 0 0 1 412.6 370.8 Tm (feature ) Tj 1 0 0 1 447.4 370.8 Tm (at ) Tj 1 0 0 1 459.4 370.8 Tm (29022 ) Tj 1 0 0 1 488.7 370.8 Tm (cm-1.S) Tj 1 0 0 1 79.2 357.6 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1 0 0 1 274.8 345.1 Tm (seen ) Tj 1 0 0 1 299.3 345.1 Tm (that ) Tj 1 0 0 1 318.0 345.1 Tm (the ) Tj 1 0 0 1 335.5 345.1 Tm (low ) Tj 1 0 0 1 352.3 345.1 Tm (energy ) Tj 1 0 0 1 385.0 345.1 Tm (region ) Tj 1 0 0 1 415.0 345.1 Tm (is ) Tj 1 0 0 1 425.3 345.1 Tm (rather ) Tj 1 0 0 1 453.6 345.1 Tm (complicated ) Tj 1 0 0 1 508.3 345.1 Tm (due ) Tj 1 0 0 1 527.8 345.1 Tm (to) Tj 1 0 0 1 79.5 334.1 Tm (excitation ) Tj 1 0 0 1 124.1 334.1 Tm (of ) Tj 1 0 0 1 135.6 334.1 Tm (many ) Tj 1 0 0 1 163.5 334.1 Tm (low ) Tj 1 0 0 1 181.0 334.1 Tm (frequency ) Tj 1 0 0 1 227.1 334.1 Tm (modes ) Tj 1 0 0 1 259.5 334.1 Tm (which ) Tj 1 0 0 1 287.8 334.1 Tm (involve ) Tj 1 0 0 1 321.4 334.1 Tm (skeletal ) Tj 1 0 0 1 357.4 334.1 Tm (bending ) Tj 1 0 0 1 394.8 334.1 Tm (vibrations ) Tj 1 0 0 1 440.2 334.1 Tm (and ) Tj 1 0 0 1 460.1 334.1 Tm (methyl ) Tj 1 0 0 1 491.3 334.1 Tm (torsions.) Tj 1 0 0 1 79.5 321.8 Tm (Many ) Tj 1 0 0 1 107.1 321.8 Tm (low ) Tj 1 0 0 1 124.3 321.8 Tm (freguency ) Tj 1 0 0 1 170.7 321.8 Tm (modes ) Tj 1 0 0 1 202.8 321.8 Tm (derive ) Tj 1 0 0 1 234.3 321.8 Tm (intensity ) Tj 1 0 0 1 272.4 321.8 Tm (from ) Tj 1 0 0 1 295.9 321.8 Tm (Herzberg-Teller ) Tj 1 0 0 1 365.3 321.8 Tm (coupling ) Tj 1 0 0 1 404.9 321.8 Tm (between ) Tj 1 0 0 1 444.7 321.8 Tm (the ) Tj 1 0 0 1 462.3 321.8 Tm (21 ) Tj 1 0 0 1 472.6 321.8 Tm (Ag ) Tj 1 0 0 1 487.7 321.8 Tm (and ) Tj 1 0 0 1 506.4 321.8 Tm (11 ) Tj 1 0 0 1 517.2 321.8 Tm (Bu) Tj 1 0 0 1 79.5 308.2 Tm (states, ) Tj 1 0 0 1 111.4 308.2 Tm (which ) Tj 1 0 0 1 140.2 308.2 Tm (makes ) Tj 1 0 0 1 172.1 308.2 Tm (the ) Tj 1 0 0 1 189.9 308.2 Tm (21 ) Tj 1 0 0 1 200.2 308.2 Tm (Ag ) Tj 1 0 0 1 215.5 308.2 Tm (\(- ) Tj 1 0 0 1 228.0 308.2 Tm (11 ) Tj 1 0 0 1 237.9 308.2 Tm (Ag ) Tj 1 0 0 1 254.2 308.2 Tm (symmetry ) Tj 1 0 0 1 300.0 308.2 Tm (forbidden ) Tj 1 0 0 1 344.2 308.2 Tm (transition ) Tj 1 0 0 1 388.6 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(weakly ) Tj 1 0 0 1 326.4 284.9 Tm (allowed. ) Tj 1 0 0 1 369.6 284.9 Tm (The ) Tj 1 0 0 1 389.8 284.9 Tm (characteristic ) Tj 1 0 0 1 450.5 284.9 Tm (signature ) Tj 1 0 0 1 494.4 284.9 Tm (of ) Tj 1 0 0 1 506.2 284.9 Tm (methyl) Tj 1 0 0 1 79.2 272.6 Tm (torsion ) Tj 1 0 0 1 113.1 272.6 Tm (induced ) Tj 1 0 0 1 151.0 272.6 Tm (transitions ) Tj 1 0 0 1 200.2 272.6 Tm (is ) Tj 1 0 0 1 211.9 272.6 Tm (a ) Tj 1 0 0 1 222.3 272.6 Tm (triplet ) Tj 1 0 0 1 250.3 272.6 Tm (structure ) Tj 1 0 0 1 292.1 272.6 Tm (with ) Tj 1 0 0 1 313.7 272.6 Tm (a ) Tj 1 0 0 1 324.0 272.6 Tm (3.4 ) Tj 1 0 0 1 341.1 272.6 Tm (cm-1 ) Tj 1 0 0 1 366.7 272.6 Tm (splitting ) Tj 1 0 0 1 403.7 272.6 Tm (\(doublet ) Tj 1 0 0 1 442.8 272.6 Tm (in ) Tj 1 0 0 1 454.8 272.6 Tm (case ) Tj 1 0 0 1 480.5 272.6 Tm (of) Tj 1 0 0 1 78.7 261.6 Tm (nonatetraene, ) Tj 1 0 0 1 142.6 261.6 Tm (which ) Tj 1 0 0 1 171.4 261.6 Tm (has ) Tj 1 0 0 1 191.5 261.6 Tm (only ) Tj 1 0 0 1 212.7 261.6 Tm (one ) Tj 1 0 0 1 233.3 261.6 Tm (methyl\); ) Tj 1 0 0 1 271.2 261.6 Tm (for ) Tj 1 0 0 1 286.6 261.6 Tm (the ) Tj 1 0 0 1 304.1 261.6 Tm (transitions ) Tj 1 0 0 1 351.6 261.6 Tm (which ) Tj 1 0 0 1 380.4 261.6 Tm (are ) Tj 1 0 0 1 398.4 261.6 Tm (induced ) Tj 1 0 0 1 436.1 261.6 Tm (by ) Tj 1 0 0 1 450.5 261.6 Tm (bu ) Tj 1 0 0 1 465.9 261.6 Tm (symmetry ) Tj 1 0 0 1 512.4 261.6 Tm (in-) Tj 1 0 0 1 79.5 249.6 Tm (plane ) Tj 1 0 0 1 106.3 249.6 Tm (bending ) Tj 1 0 0 1 144.0 249.6 Tm (the ) Tj 1 0 0 1 161.3 249.6 Tm (signature ) Tj 1 0 0 1 204.7 249.6 Tm (is ) Tj 1 0 0 1 215.3 249.6 Tm (a ) Tj 1 0 0 1 224.9 249.6 Tm (singlet ) Tj 1 0 0 1 255.1 249.6 Tm (structure. ) Tj 1 0 0 1 303.4 249.6 Tm (High ) Tj 1 0 0 1 326.4 249.6 Tm (resolution ) Tj 1 0 0 1 371.1 249.6 Tm (fluorescence ) Tj 1 0 0 1 428.9 249.6 Tm (excitation ) Tj 1 0 0 1 473.5 249.6 Tm (spectra ) Tj 1 0 0 1 509.3 249.6 Tm (of ) Tj 1 0 0 1 521.1 249.6 Tm (DT) Tj 1 0 0 1 79.7 237.4 Tm (and ) Tj 1 0 0 1 99.6 237.4 Tm (NT ) Tj 1 0 0 1 115.0 237.4 Tm (S1 ) Tj 1 0 0 1 129.6 237.4 Tm (\(- ) Tj 1 0 0 1 141.6 237.4 Tm (So ) Tj 1 0 0 1 155.3 237.4 Tm (origin ) Tj 1 0 0 1 182.7 237.4 Tm (regions ) Tj 1 0 0 1 217.5 237.4 Tm (are ) Tj 1 0 0 1 235.0 237.4 Tm (shown ) Tj 1 0 0 1 265.7 237.4 Tm (in ) Tj 1 0 0 1 277.0 237.4 Tm (Fig. ) Tj 1 0 0 1 295.0 237.4 Tm (4. ) Tj 1 0 0 1 310.3 237.4 Tm (The ) Tj 1 0 0 1 331.5 237.4 Tm (-3.4 ) Tj 1 0 0 1 352.1 237.4 Tm (cm-1 ) Tj 1 0 0 1 375.9 237.4 Tm (splitting ) Tj 1 0 0 1 411.6 237.4 Tm (is ) Tj 1 0 0 1 421.7 237.4 Tm (due ) Tj 1 0 0 1 441.4 237.4 Tm (to ) Tj 1 0 0 1 452.9 237.4 Tm (the ) Tj 1 0 0 1 469.9 237.4 Tm (tunneling ) Tj 1 0 0 1 512.9 237.4 Tm (of ) Tj 1 0 0 1 524.2 237.4 Tm (two) Tj 1 0 0 1 80.4 225.1 Tm (equivalent ) Tj 1 0 0 1 127.2 225.1 Tm (methyl ) Tj 1 0 0 1 158.4 225.1 Tm (groups ) Tj 1 0 0 1 191.5 225.1 Tm (through ) Tj 1 0 0 1 228.0 225.1 Tm (a ) Tj 1 0 0 1 237.9 225.1 Tm (low ) Tj 1 0 0 1 255.1 225.1 Tm (barrier ) Tj 1 0 0 1 286.3 225.1 Tm (on ) Tj 1 0 0 1 300.5 225.1 Tm (the ) Tj 1 0 0 1 317.5 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551.0 Tm (absorption ) Tj 1 0 0 1 343.7 551.0 Tm (due ) Tj 1 0 0 1 362.6 551.0 Tm (to ) Tj 1 0 0 1 373.4 551.0 Tm (the ) Tj 1 0 0 1 389.5 551.0 Tm (steeper ) Tj 1 0 0 1 424.1 551.0 Tm (slope ) Tj 1 0 0 1 450.0 551.0 Tm (of ) Tj 1 0 0 1 460.1 551.0 Tm (the ) Tj 1 0 0 1 476.4 551.0 Tm (S1 ) Tj 1 0 0 1 490.6 551.0 Tm (state) Tj 1 0 0 1 73.9 539.3 Tm (potential ) Tj 1 0 0 1 113.3 539.3 Tm (energy ) Tj 1 0 0 1 145.4 539.3 Tm (surface ) Tj 1 0 0 1 180.2 539.3 Tm (in ) Tj 1 0 0 1 191.0 539.3 Tm (the ) Tj 1 0 0 1 207.6 539.3 Tm (CC ) Tj 1 0 0 1 224.6 539.3 Tm (stretching ) Tj 1 0 0 1 268.8 539.3 Tm (C> stream x]=oG!`p,.7q@S/yazG2) @R C` 8ڀh, I$O9=ު%e]}Ͻ~|4m-{^Dӽ7fwz~~!-5ԁ˰jlNg:C$m>+̳ٚ6ܳ}< %~aR?;aג;% 8+E|Ų$~W~Tĕ_goR?QApUw8I㟿{?@3/|(o[` ڧ(NX#.>3MsK/cųX_߂*Rg8tM>~;7՟OR1_pl Y/'߈_}cGf N?}&dWA:T|ANO$_7W[)?֒A VlIxP\ ޺gQ}ͿC{mWx]lZ'@s]N\?o`f?_?߀m޾_V _KYbR +o 녿H0vBi3s'RJf]v6-튢Pڟp;O_,֯߹sLSc/6*m#'hjnm_G`L`C;q?Ύqq|8(sAWL6s򒠌 /Vn[KsgBZ/KeKś)A:s;:[Ư+L?ISߙݗOŧS71, 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Pno 냞QúSm.0%/rt]ij6Uw\o͇kvVڨz  zޘ~ba v 9O2u#}0[|w*@HPswN=x^xHpnG?D`,/"zFZ@ٜIoH 0 znKl5G㔐H}#I]{KmakjIewć)gyC _*}'Z endstream endobj 462 0 obj << /Length 779 /Filter [ /FlateDecode ] >> stream x  !!!"""###$$$%%%&&&'''((()))***+++,,,---...///000111222333444555666777888999:::;;;<<<===>>>???@@@AAABBBCCCDDDEEEFFFGGGHHHIIIJJJKKKLLLMMMNNNOOOPPPQQQRRRSSSTTTUUUVVVWWWXXXYYYZZZ[[[\\\]]]^^^___```aaabbbcccdddeeefffggghhhiiijjjkkklllmmmnnnooopppqqqrrrssstttuuuvvvwwwxxxyyyzzz{{{|||}}}~~~b~ endstream endobj 461 0 obj << /Length 105 /Filter [ /FlateDecode ] >> stream xU1@ 2/pwH4)@c BflO̲$O2cIE4dqPxEZŽt6'fS%FwpHwxQ# b endstream endobj 463 0 obj << /Type /XObject /Subtype /Image /Name /Ob463 /Width 68 /Height 752 /BitsPerComponent 8 /Length 5360 /ColorSpace [ /Indexed /DeviceRGB 255 465 0 R ] /Filter [ /FlateDecode ] >> stream x]Mk׶_M|RO'/#ĉ p#!Oc0(eB; DX7R&"X&ϊA6I&Z Bgj, ԧ:pSqjkGowF(}_w9TEc^&q0AL<B1a,p,5t18cTeE} baazhn;]4b@y-zyH^HS忏a[,)W>T%A#}=(# )ԥ. 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T8$LՏfz"nî}#vɃck'*zv1 1-Xk*ʧv( + 7xpOtArITk6` 8s Y.:_2@>Gp{߈ù#W\t])RvMyO~W~KE56\\ȟ#p!j^ .k e| ϠA8Q&oTKU0?]NYjV*6Dl-FƵ;q+JzJtlspJpn*gDZ_SueӇ΋ r'% 7gHIV֘Ifِ&3*K.fY];eޓAm='NHTo.)iX\MFܒ3ImOI;ms4d8\Q)tU^CmL .^<.gRcvpɺW! yd>A )34L[YJ3^d.\ؔ" bOA _A:=N;>[#se`$R:\M, kA3 ܙmW͞@bQ$8L1*=^ՄR d܌!Zʼ2C\FWF5.+eP'_pϸv;y.7Z.g5pQ-W&]:uֶzpt9VjvW}z7E64O4gjw  pe. =)'ǂ|o rWr_0;usǟH):ȿ/Ywٮ-ݏ;><'+Ӱ'sOvHpEL•0OW}CO Qi癦>ܘ{}j+3jm ܶ$>/b"ݶ$>/ҽ#UFٽ`i[ktw/u#]͙o n;ݎy)>;IﺉG[_޴ 6!x5uR bnenC}[)GIZ ܎uHLb;}nOm2cJ*{oOVw;|+_/]'Hڕh2vL]j:j8%kGlJ'K6l@Vcoy˨f[^'-ܻrv^~cH8зT 쵸#pz#sG5U GluᘿCY8Cx~9#XoM̎t,{ *e,amV(.B&+X,y|Y+ ;L9=+u RzHM >?溛Wѽ1B i^jw]&_vGN@@X>wVʠzXmZ*Y tYYɕbV,P*-YCd3W%c}б$K!kp}CWhM MlЛf,xo_KLGd c󴙲PGK, C~1flVA} "ӰزѠs\0/W’<"9lm /w\B<B'7-Z-pR ZDZ@ls#ҽ'ܥh(JY.GB<Bppᯈdp+l,TdEF7p<U.4.L_ cn/P!RlrA2U2 +eU{!cgt7щ[))3~r f7 ]2F݁{x-i)6XoǒLyC7n*M 1E"a{,ѐ#6@_P7c zWͰHQ")55tV endstream endobj 537 0 obj << /Length 251 /Filter [ /FlateDecode ] >> stream xM;n1 NP &+_ߤHnv1Q"xᎌO:xDbR BT2紞*,ĩ>]Օx9'sL[[-s2ǭHQde~!]-@嫤mGOnFMsN!9MKsqdήy rW\Ugwvf4kwAF]9i,y`OHӓbaHu[pjx\H endstream endobj 538 0 obj << /Length 3833 >> stream q BT 3 Tr /FontHelvetica 9.0 Tf 1 0 0 1 109.2 471.3 Tm (The ) Tj 1 0 0 1 128.4 471.3 Tm (measured ) Tj 1 0 0 1 172.8 471.3 Tm (fluorescence ) Tj 1 0 0 1 228.7 471.3 Tm (decay ) Tj 1 0 0 1 257.0 471.3 Tm (rates ) Tj 1 0 0 1 280.3 471.3 Tm (as ) Tj 1 0 0 1 293.0 471.3 Tm (a ) Tj 1 0 0 1 300.9 471.3 Tm (function ) Tj 1 0 0 1 336.9 471.3 Tm (of ) Tj 1 0 0 1 347.0 471.3 Tm (excess ) Tj 1 0 0 1 379.2 471.3 Tm (energy ) Tj 1 0 0 1 410.6 471.3 Tm (for ) Tj 1 0 0 1 425.7 471.3 Tm (DT ) Tj 1 0 0 1 440.4 471.3 Tm (and ) Tj 1 0 0 1 459.6 471.3 Tm (NT ) Tj 1 0 0 1 474.2 471.3 Tm (are ) Tj 1 0 0 1 490.5 471.3 Tm (displayed) Tj 1 0 0 1 77.5 461.0 Tm (in ) Tj 1 0 0 1 87.6 461.0 Tm (Fig. ) Tj 1 0 0 1 106.5 461.0 Tm (3. ) Tj 1 0 0 1 122.4 461.0 Tm (For ) Tj 1 0 0 1 139.4 461.0 Tm (both ) Tj 1 0 0 1 162.4 461.0 Tm (DT ) Tj 1 0 0 1 177.3 461.0 Tm (and ) Tj 1 0 0 1 197.2 461.0 Tm (NT ) Tj 1 0 0 1 212.1 461.0 Tm (the ) Tj 1 0 0 1 228.7 461.0 Tm (fluorescence ) Tj 1 0 0 1 285.8 461.0 Tm (lifetimes ) Tj 1 0 0 1 323.7 461.0 Tm (are ) Tj 1 0 0 1 340.8 461.0 Tm (seen ) Tj 1 0 0 1 364.3 461.0 Tm (to ) Tj 1 0 0 1 375.6 461.0 Tm (decrease ) Tj 1 0 0 1 418.0 461.0 Tm (from ) Tj 1 0 0 1 441.8 461.0 Tm (-350 ) Tj 1 0 0 1 466.0 461.0 Tm (ns ) Tj 1 0 0 1 480.0 461.0 Tm (at ) Tj 1 0 0 1 490.3 461.0 Tm (the ) Tj 1 0 0 1 507.1 461.0 Tm (origin) Tj 1 0 0 1 77.5 448.0 Tm (by ) Tj 1 0 0 1 91.4 448.0 Tm (approximately ) Tj 1 0 0 1 155.2 448.0 Tm (1/2 ) Tj 1 0 0 1 172.3 448.0 Tm (upon ) Tj 1 0 0 1 197.5 448.0 Tm (increasing ) Tj 1 0 0 1 244.5 448.0 Tm (the ) Tj 1 0 0 1 262.0 448.0 Tm (exce:>s ) Tj 1 0 0 1 295.6 448.0 Tm (energy ) Tj 1 0 0 1 328.3 448.0 Tm (to ) Tj 1 0 0 1 341.0 448.0 Tm (2000 ) Tj 1 0 0 1 364.8 448.0 Tm (cm-1. ) Tj 1 0 0 1 396.2 448.0 Tm (The ) Tj 1 0 0 1 416.6 448.0 Tm (increase ) Tj 1 0 0 1 457.2 448.0 Tm (of ) Tj 1 0 0 1 468.2 448.0 Tm (the ) Tj 1 0 0 1 485.5 448.0 Tm (radiative) Tj 1 0 0 1 77.2 437.4 Tm (decay ) Tj 1 0 0 1 105.8 437.4 Tm (rate ) Tj 1 0 0 1 125.0 437.4 Tm (as ) Tj 1 0 0 1 138.2 437.4 Tm (a ) Tj 1 0 0 1 146.6 437.4 Tm (function ) Tj 1 0 0 1 183.3 437.4 Tm (of ) Tj 1 0 0 1 194.8 437.4 Tm (52 ) Tj 1 0 0 1 207.8 437.4 Tm (-51 ) Tj 1 0 0 1 228.4 437.4 Tm (separation ) Tj 1 0 0 1 276.0 437.4 Tm (is ) Tj 1 0 0 1 286.5 437.4 Tm (commonly ) Tj 1 0 0 1 331.6 437.4 Tm (observed ) Tj 1 0 0 1 374.1 437.4 Tm (in ) Tj 1 0 0 1 384.7 437.4 Tm (the ) Tj 1 0 0 1 401.2 437.4 Tm (51 ) Tj 1 0 0 1 415.6 437.4 Tm (states ) Tj 1 0 0 1 445.2 437.4 Tm (of ) Tj 1 0 0 1 455.7 437.4 Tm (polyenes ) Tj 1 0 0 1 497.2 437.4 Tm (in) Tj 1 0 0 1 77.5 424.2 Tm (solution ) Tj 1 0 0 1 114.0 424.2 Tm (and ) Tj 1 0 0 1 133.4 424.2 Tm (is ) Tj 1 0 0 1 144.0 424.2 Tm (attributed ) Tj 1 0 0 1 187.2 424.2 Tm (to ) Tj 1 0 0 1 198.9 424.2 Tm (the ) Tj 1 0 0 1 216.9 424.2 Tm (intensity ) Tj 1 0 0 1 254.6 424.2 Tm (borrowing ) Tj 1 0 0 1 300.0 424.2 Tm (between ) Tj 1 0 0 1 340.3 424.2 Tm (52 ) Tj 1 0 0 1 354.0 424.2 Tm (and ) Tj 1 0 0 1 372.9 424.2 Tm (51 ) Tj 1 0 0 1 387.3 424.2 Tm (states.1 ) Tj 1 0 0 1 428.1 424.2 Tm (For ) Tj 1 0 0 1 446.4 424.2 Tm (NT ) Tj 1 0 0 1 461.0 424.2 Tm (there ) Tj 1 0 0 1 486.4 424.2 Tm (is ) Tj 1 0 0 1 496.8 424.2 Tm (a ) Tj 1 0 0 1 505.4 424.2 Tm (large) Tj 1 0 0 1 77.2 412.7 Tm (quantum ) Tj 1 0 0 1 116.6 412.7 Tm (state ) Tj 1 0 0 1 139.4 412.7 Tm (dependence ) Tj 1 0 0 1 194.4 412.7 Tm (in ) Tj 1 0 0 1 204.2 412.7 Tm (the ) Tj 1 0 0 1 220.0 412.7 Tm (decay ) Tj 1 0 0 1 248.6 412.7 Tm (rates ) Tj 1 0 0 1 271.6 412.7 Tm (in ) Tj 1 0 0 1 281.7 412.7 Tm (the ) Tj 1 0 0 1 298.3 412.7 Tm (low ) Tj 1 0 0 1 314.4 412.7 Tm (energy ) Tj 1 0 0 1 345.1 412.7 Tm (region, ) Tj 1 0 0 1 377.2 412.7 Tm (as ) Tj 1 0 0 1 389.7 412.7 Tm (discussed ) Tj 1 0 0 1 434.4 412.7 Tm (above.) 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Tm (trans-cis ) Tj 1 0 0 1 200.8 320.6 Tm (isomerization ) Tj 1 0 0 1 261.1 320.6 Tm (of ) Tj 1 0 0 1 273.1 320.6 Tm (DT ) Tj 1 0 0 1 288.2 320.6 Tm (and ) Tj 1 0 0 1 308.3 320.6 Tm (NT ) Tj 1 0 0 1 323.7 320.6 Tm (under ) Tj 1 0 0 1 351.8 320.6 Tm (isolated ) Tj 1 0 0 1 387.8 320.6 Tm (conditions ) Tj 1 0 0 1 434.8 320.6 Tm (or ) Tj 1 0 0 1 447.3 320.6 Tm (in ) Tj 1 0 0 1 457.9 320.6 Tm (solution, ) Tj 1 0 0 1 497.9 320.6 Tm (Kohler) Tj 1 0 0 1 77.7 310.0 Tm (and ) Tj 1 0 0 1 97.4 310.0 Tm (coworkers ) Tj 1 0 0 1 145.1 310.0 Tm (have ) Tj 1 0 0 1 169.9 310.0 Tm (extensively ) Tj 1 0 0 1 221.2 310.0 Tm (studied ) Tj 1 0 0 1 256.5 310.0 Tm (cis-trans ) Tj 1 0 0 1 297.5 310.0 Tm (isomerization ) Tj 1 0 0 1 358.0 310.0 Tm (of ) Tj 1 0 0 1 369.3 310.0 Tm (several ) Tj 1 0 0 1 404.1 310.0 Tm (octatetraene ) Tj 1 0 0 1 462.2 310.0 Tm (isomers ) Tj 1 0 0 1 499.9 310.0 Tm (in ) Tj 1 0 0 1 512.1 310.0 Tm (low) Tj 1 0 0 1 77.7 297.5 Tm (temperature ) Tj 1 0 0 1 134.6 297.5 Tm (mixed ) Tj 1 0 0 1 164.6 297.5 Tm (crystals.13 ) Tj 1 0 0 1 218.3 297.5 Tm (Since ) Tj 1 0 0 1 246.4 297.5 Tm (isomerization ) Tj 1 0 0 1 306.9 297.5 Tm (of ) Tj 1 0 0 1 318.2 297.5 Tm (octatetraene ) Tj 1 0 0 1 375.8 297.5 Tm (is ) Tj 1 0 0 1 386.3 297.5 Tm (well ) Tj 1 0 0 1 406.5 297.5 Tm (established, ) Tj 1 0 0 1 462.7 297.5 Tm (we ) Tj 1 0 0 1 479.0 297.5 Tm (tentatively) Tj 1 0 0 1 77.9 287.0 Tm (assign ) Tj 1 0 0 1 108.9 287.0 Tm (this ) Tj 1 0 0 1 127.6 287.0 Tm (nonradiative ) Tj 1 0 0 1 184.0 287.0 Tm (decay ) Tj 1 0 0 1 212.3 287.0 Tm (process ) Tj 1 0 0 1 249.5 287.0 Tm (to ) Tj 1 0 0 1 262.3 287.0 Tm (cis-tr,ins ) Tj 1 0 0 1 301.6 287.0 Tm (isomerization. ) Tj 1 0 0 1 367.6 287.0 Tm (Since ) Tj 1 0 0 1 395.0 287.0 Tm (the ) Tj 1 0 0 1 413.2 287.0 Tm (IVA ) Tj 1 0 0 1 431.9 287.0 Tm (rate ) Tj 1 0 0 1 452.1 287.0 Tm (is ) Tj 1 0 0 1 462.4 287.0 Tm (much ) Tj 1 0 0 1 489.1 287.0 Tm (faster ) Tj 1 0 0 1 516.7 287.0 Tm (than) Tj 1 0 0 1 77.7 274.7 Tm (the ) Tj 1 0 0 1 94.0 274.7 Tm (fluorescence ) Tj 1 0 0 1 151.1 274.7 Tm (decay ) Tj 1 0 0 1 180.4 274.7 Tm (rate ) Tj 1 0 0 1 201.1 274.7 Tm (at ) Tj 1 0 0 1 212.1 274.7 Tm (2000 ) Tj 1 0 0 1 235.6 274.7 Tm (cm-1 ) Tj 1 0 0 1 260.3 274.7 Tm (exces~; ) Tj 1 0 0 1 291.5 274.7 Tm (energy, ) Tj 1 0 0 1 327.8 274.7 Tm (it ) Tj 1 0 0 1 334.7 274.7 Tm (is ) Tj 1 0 0 1 344.8 274.7 Tm (a ) Tj 1 0 0 1 353.2 274.7 Tm (good ) Tj 1 0 0 1 377.7 274.7 Tm (assumption ) Tj 1 0 0 1 430.3 274.7 Tm (that ) Tj 1 0 0 1 449.0 274.7 Tm (the ) Tj 1 0 0 1 465.8 274.7 Tm (energy ) Tj 1 0 0 1 497.9 274.7 Tm (is) Tj 1 0 0 1 77.7 263.7 Tm (statistically ) Tj 1 0 0 1 128.6 263.7 Tm (distributed ) Tj 1 0 0 1 178.0 263.7 Tm (in ) Tj 1 0 0 1 189.5 263.7 Tm (all ) Tj 1 0 0 1 203.9 263.7 Tm (of ) Tj 1 0 0 1 215.9 263.7 Tm (the ) Tj 1 0 0 1 233.9 263.7 Tm (available ) Tj 1 0 0 1 275.7 263.7 Tm (vit\)rational ) Tj 1 0 0 1 323.7 263.7 Tm (degrees ) Tj 1 0 0 1 363.1 263.7 Tm (of ) Tj 1 0 0 1 374.3 263.7 Tm (freedom, ) Tj 1 0 0 1 417.5 263.7 Tm (and ) Tj 1 0 0 1 438.7 263.7 Tm (that ) Tj 1 0 0 1 458.3 263.7 Tm (the ) Tj 1 0 0 1 476.3 263.7 Tm (barrier ) Tj 1 0 0 1 508.3 263.7 Tm (to) Tj 1 0 0 1 77.9 252.9 Tm (isomerization ) Tj 1 0 0 1 137.2 252.9 Tm (is ) Tj 1 0 0 1 147.5 252.9 Tm (located ) Tj 1 0 0 1 181.1 252.9 Tm (where ) Tj 1 0 0 1 210.2 252.9 Tm (the ) Tj 1 0 0 1 227.2 252.9 Tm (decay ) Tj 1 0 0 1 256.0 252.9 Tm (rate ) Tj 1 0 0 1 275.5 252.9 Tm (begins ) Tj 1 0 0 1 306.4 252.9 Tm (to ) Tj 1 0 0 1 317.9 252.9 Tm (increase ) Tj 1 0 0 1 356.6 252.9 Tm (rapidly. ) Tj 1 0 0 1 394.5 252.9 Tm (The ) Tj 1 0 0 1 414.4 252.9 Tm (faster ) Tj 1 0 0 1 441.8 252.9 Tm (fluorescence ) Tj 1 0 0 1 499.4 252.9 Tm (decay) Tj 1 0 0 1 78.2 242.3 Tm (rate ) Tj 1 0 0 1 97.9 242.3 Tm (and ) Tj 1 0 0 1 116.8 242.3 Tm (greater ) Tj 1 0 0 1 150.9 242.3 Tm (loss ) Tj 1 0 0 1 171.5 242.3 Tm (of ) Tj 1 0 0 1 182.6 242.3 Tm (intensity ) Tj 1 0 0 1 221.2 242.3 Tm (in ) Tj 1 0 0 1 233.0 242.3 Tm (NT ) Tj 1 0 0 1 248.3 242.3 Tm (as ) Tj 1 0 0 1 261.5 242.3 Tm 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GO־E-l@U\dAƏ7rZrq!Ӷ( [}kʉ+'薱녘Qij1r.Iɢc1,9g7a,23\M؃5:H=()J$'X΂9Ο\j4wyTay͓ͧT> r "KGo"տg[i->7O2[F]5q.3QkVԎ m(YA78ɹc.Gqg=#TmbBEl'p曤H$ƶT,q()fBjwio7̞]vkj v[c^Բ9Hjvwò{l;Ni{Ԅ<.AsҦJYErKOEp31/M'3ڵ%evIC\lwY*!ۖg1 9GWԘ9挟rEbUa Ww)g̾c~C3u ״ .lW1<i˕=i,ˌd: 2r:>fK,Dzۗv갰3[!]M%Syb/ՒlcNoI8NO 2NSDaNl^fv2m y(G Prv)=Pb?*$ߴ6޴0i=v8Cf* СE:D\'ѳBjq$0g?q ٖoP٫MV obbMː f)2ܲl}mJ%@U+ٮs{ruC"$<\W V H6Pu#9YŅz_zl=E:L4I.'ž3뛓jTrEvN@xfbWlv;Bm:0YB-nZs7UmUfSSeVy6撉cZΉ%IeǠVON4ɽuDV1Z}jy{1NGE͍O<~]'L$9*ڰ칋-6ڤNdǬ:ɹ'$ծpؗ^+əܘ$q.~Ǣ&zвԐ+wkH0ӄ$~Z 3`> EDtN5{D.RU6 m5)0i蓐e:d11cߞ#c^nEIS*8J2sD{ɾ4Ppf9jJ c.C{jʶn$L.&t̮($C¬V6|.ǘoҸ|f̎6 b;r0{Aof6T6efFỷڈ cfX3p2j|>!'dMӔcztLutQ 󄌞O0gp6I]dw1q9Ɋ h.U`ؤ =m'+YcVM<eeC>%ۘO.꒽uf n`i F3sIΤ,̤Z:Th]@I"oC/濢 s \'1N۟t{R'Vuл9+wq[3˔+̢WuT?s(jkVXA=e^^$cwqTXqf30EbWk'A?PڜYQ?1/X]&dt'/ń_uSYcWm O)}0IRv8r'ǜnjܝ= le ҄*Z9[`̬ܞ*Z:,%KJѝmSR fTgP!P*m!H$cNd̢TeU>Cv,m9h:C(͐]ϖ9yh_mAɀƩO0f"ÌR-עDe*wXŞn'ͤI1Sg0jKԁsvY1w1lsfۨ 64l)2Ul0|ȹcNѬncV*k9 H9zpX:G# :S ǻMSЄ1K}.D;ê㠏!RzamrcNc|2W%kc6"rBlA"ʘ]+f%jkQZm戥,RV7sDy}Fktühi[S=r0Fጕr2ReV2G25\J![@Q 3,d ].8ߚ5w#x>r0hʘCEyr"ؙu 7  WGV˂flb[Ly_V铒Cr3̌jv̡Yi(l*M]?/+򓢤}@ⱱW\nއqY~ΛCώ/Fq`_E/QX܇9۹0so{G- ?WI|~Aey`=ŰB^&:8蜙v\tzʙlgHhabYsTr s8e4M:ؼ0N2fg¬|tU9nQ~$%#h+3g 6d懕M ?E+UNw6fabG <ϣyDq<1rի1k. $ϒzވbŠC$vgFN*>1Ydg*s9(,AQUJ栚pɸ{c֞V@bQvsd$EC!6VFf\ŭf;G3o/) endstream endobj 686 0 obj << /Length 299 /Filter [ /FlateDecode ] >> stream xU;N1 E|(=4 Q}|=3g{wn؏\q窹 .Ym2g}sԞvڿ`0/Y(X| J978xK1ao$};HD*5.{馏Fz}4M۪< endstream endobj 687 0 obj << /Length 15141 >> stream q BT 3 Tr /FontHelvetica 10.0 Tf 1 0 0 1 78.9 489.3 Tm (1. ) Tj 1 0 0 1 90.0 489.3 Tm (B. ) Tj 1 0 0 1 102.7 489.3 Tm (S. ) Tj 1 0 0 1 115.6 489.3 Tm (Hudson, ) Tj 1 0 0 1 154.5 489.3 Tm (B. ) Tj 1 0 0 1 167.0 489.3 Tm (E. ) Tj 1 0 0 1 179.2 489.3 Tm (Kohler, ) Tj 1 0 0 1 214.0 489.3 Tm (K. ) Tj 1 0 0 1 226.0 489.3 Tm (Schulten, ) Tj 1 0 0 1 269.5 489.3 Tm ("Linear ) Tj 1 0 0 1 302.8 489.3 Tm (polyene ) Tj 1 0 0 1 339.3 489.3 Tm (electronic ) Tj 1 0 0 1 383.2 489.3 Tm (structures ) Tj 1 0 0 1 428.8 489.3 Tm (and ) Tj 1 0 0 1 448.3 489.3 Tm (potential) Tj 1 0 0 1 68.4 478.5 Tm (Surfaces," ) Tj 1 0 0 1 116.8 478.5 Tm (in ) Tj 1 0 0 1 128.4 478.5 Tm (Excited ) Tj 1 0 0 1 164.6 478.5 Tm (States. ) Tj 1 0 0 1 198.2 478.5 Tm (ed. ) Tj 1 0 0 1 216.0 478.5 Tm (E. ) Tj 1 0 0 1 228.9 478.5 Tm (C. ) Tj 1 0 0 1 241.9 478.5 Tm (Lim, ) Tj 1 0 0 1 263.5 478.5 Tm (vol ) Tj 1 0 0 1 280.5 478.5 Tm (6, ) Tj 1 0 0 1 291.3 478.5 Tm (pp ) Tj 1 0 0 1 306.9 478.5 Tm (1-95, ) Tj 1 0 0 1 330.4 478.5 Tm (Academic ) Tj 1 0 0 1 375.6 478.5 Tm (Press, ) Tj 1 0 0 1 407.7 478.5 Tm (New ) Tj 1 0 0 1 429.6 478.5 Tm (York ) Tj 1 0 0 1 452.8 478.5 Tm (\(1982\).) 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Tj 1 0 0 1 77.5 412.0 Tm (4. ) Tj 1 0 0 1 89.2 412.0 Tm (H. ) Tj 1 0 0 1 103.4 412.0 Tm (Petek, ) Tj 1 0 0 1 131.5 412.0 Tm (A. ) Tj 1 0 0 1 143.7 412.0 Tm (J. ) Tj 1 0 0 1 155.0 412.0 Tm (Bell, ) Tj 1 0 0 1 177.1 412.0 Tm (R. ) Tj 1 0 0 1 189.8 412.0 Tm (L. ) Tj 1 0 0 1 200.8 412.0 Tm (Christensen, ) Tj 1 0 0 1 258.0 412.0 Tm (and ) Tj 1 0 0 1 276.2 412.0 Tm (K. ) Tj 1 0 0 1 288.2 412.0 Tm (Yoshihara, ) Tj 1 0 0 1 336.7 412.0 Tm ("Fluorescence ) Tj 1 0 0 1 400.0 412.0 Tm (excitation ) Tj 1 0 0 1 443.2 412.0 Tm (spectra ) Tj 1 0 0 1 478.5 412.0 Tm (of ) Tj 1 0 0 1 489.3 412.0 Tm (the ) Tj 1 0 0 1 505.9 412.0 Tm (S1) Tj 1 0 0 1 68.4 400.0 Tm (states ) Tj 1 0 0 1 98.4 400.0 Tm (of ) Tj 1 0 0 1 110.1 400.0 Tm (isolated ) Tj 1 0 0 1 146.8 400.0 Tm (trienes," ) Tj 1 0 0 1 186.0 400.0 Tm (J. ) Tj 1 0 0 1 198.0 400.0 Tm (Chern. ) Tj 1 0 0 1 229.4 400.0 Tm (Phys. ) Tj 1 0 0 1 257.0 400.0 Tm (\(in ) Tj 1 0 0 1 271.6 400.0 Tm (prE~ss\).) Tj 1 0 0 1 77.0 389.7 Tm (5. ) Tj 1 0 0 1 88.8 389.7 Tm (H. ) Tj 1 0 0 1 101.5 389.7 Tm (Petek, ) Tj 1 0 0 1 130.8 389.7 Tm (A. ) Tj 1 0 0 1 143.0 389.7 Tm (J. ) Tj 1 0 0 1 154.3 389.7 Tm (Bell, ) Tj 1 0 0 1 175.6 389.7 Tm (K. ) Tj 1 0 0 1 187.6 389.7 Tm (Yoshihara, ) Tj 1 0 0 1 237.1 389.7 Tm (and ) Tj 1 0 0 1 255.6 389.7 Tm (R. ) Tj 1 0 0 1 268.3 389.7 Tm (L. ) Tj 1 0 0 1 278.8 389.7 Tm (C;hristensen, ) Tj 1 0 0 1 335.0 389.7 Tm ("Spectroscopic ) Tj 1 0 0 1 400.8 389.7 Tm (and ) Tj 1 0 0 1 419.5 389.7 Tm (dynamical ) Tj 1 0 0 1 465.8 389.7 Tm (studies ) Tj 1 0 0 1 499.6 389.7 Tm (of ) Tj 1 0 0 1 510.0 389.7 Tm (the) Tj 1 0 0 1 68.4 378.9 Tm (S1 ) Tj 1 0 0 1 84.0 378.9 Tm (and.S2 ) Tj 1 0 0 1 117.8 378.9 Tm (states ) Tj 1 0 0 1 147.6 378.9 Tm (of ) Tj 1 0 0 1 158.8 378.9 Tm (decatetraene ) Tj 1 0 0 1 219.3 378.9 Tm (in ) Tj 1 0 0 1 230.4 378.9 Tm (supersonic ) Tj 1 0 0 1 280.5 378.9 Tm (molecular ) Tj 1 0 0 1 325.2 378.9 Tm (beams," ) Tj 1 0 0 1 363.3 378.9 Tm (J. ) Tj 1 0 0 1 374.8 378.9 Tm (Chern. ) Tj 1 0 0 1 406.3 378.9 Tm (Phys. ) Tj 1 0 0 1 434.1 378.9 Tm (95, ) Tj 1 0 0 1 451.9 378.9 Tm (4739 ) Tj 1 0 0 1 476.4 378.9 Tm (\(1991\).) Tj 1 0 0 1 77.0 367.4 Tm (6. ) Tj 1 0 0 1 88.5 367.4 Tm (W. ) Tj 1 0 0 1 102.7 367.4 Tm (G. ) Tj 1 0 0 1 116.1 367.4 Tm (Bouwman, ) Tj 1 0 0 1 164.4 367.4 Tm (A. ) Tj 1 0 0 1 175.9 367.4 Tm (C. ) Tj 1 0 0 1 189.1 367.4 Tm (Jones, ) Tj 1 0 0 1 220.0 367.4 Tm (D. ) Tj 1 0 0 1 232.5 367.4 Tm (Phillips, ) Tj 1 0 0 1 268.3 367.4 Tm (P. ) Tj 1 0 0 1 279.8 367.4 Tm (Thibodeau, ) Tj 1 0 0 1 330.2 367.4 Tm (C. ) Tj 1 0 0 1 342.4 367.4 Tm (Friel, ) Tj 1 0 0 1 366.9 367.4 Tm (and ) Tj 1 0 0 1 385.2 367.4 Tm (R. ) Tj 1 0 0 1 397.9 367.4 Tm (L. ) Tj 1 0 0 1 408.4 367.4 Tm (Christensen, ) Tj 1 0 0 1 465.6 367.4 Tm ("Fluorescence) Tj 1 0 0 1 68.8 356.8 Tm (of ) Tj 1 0 0 1 79.9 356.8 Tm (gaseous ) Tj 1 0 0 1 120.0 356.8 Tm (tetraenes ) Tj 1 0 0 1 164.4 356.8 Tm (and ) Tj 1 0 0 1 183.8 356.8 Tm (pentaenes," ) Tj 1 0 0 1 238.8 356.8 Tm (J. ) Tj 1 0 0 1 250.5 356.8 Tm (Phys. ) Tj 1 0 0 1 278.1 356.8 Tm (Chern. ) Tj 1 0 0 1 307.9 356.8 Tm (94,7429 ) Tj 1 0 0 1 349.4 356.8 Tm (\(1990\).) Tj 1 0 0 1 77.2 346.0 Tm (7. ) Tj 1 0 0 1 88.8 346.0 Tm (W. ) Tj 1 0 0 1 102.9 346.0 Tm (J. ) Tj 1 0 0 1 114.0 346.0 Tm (Buma, ) Tj 1 0 0 1 144.4 346.0 Tm (B. ) Tj 1 0 0 1 156.9 346.0 Tm (E. ) Tj 1 0 0 1 169.4 346.0 Tm (Kohler ) Tj 1 0 0 1 200.1 346.0 Tm (and ) Tj 1 0 0 1 218.6 346.0 Tm (K. ) Tj 1 0 0 1 230.4 346.0 Tm (Song, ) Tj 1 0 0 1 259.9 346.0 Tm ("Lowest ) Tj 1 0 0 1 295.2 346.0 Tm (energy ) Tj 1 0 0 1 326.8 346.0 Tm (excited ) Tj 1 0 0 1 360.4 346.0 Tm (singlet ) Tj 1 0 0 1 390.2 346.0 Tm (state ) Tj 1 0 0 1 414.2 346.0 Tm (of ) Tj 1 0 0 1 425.2 346.0 Tm (isolated ) Tj 1 0 0 1 461.2 346.0 Tm (cis-) Tj 1 0 0 1 67.6 334.8 Tm (hexatriene,"J. ) Tj 1 0 0 1 138.4 334.8 Tm (Chern. ) Tj 1 0 0 1 173.2 334.8 Tm (Phys., ) Tj 1 0 0 1 203.2 334.8 Tm (94, ) Tj 1 0 0 1 223.6 334.8 Tm (6367 ) Tj 1 0 0 1 249.3 334.8 Tm (\(1991\).) Tj 1 0 0 1 77.7 324.4 Tm (8. ) Tj 1 0 0 1 89.5 324.4 Tm (W. ) Tj 1 0 0 1 103.6 324.4 Tm (J. ) Tj 1 0 0 1 114.9 324.4 Tm (Buma, ) Tj 1 0 0 1 145.4 324.4 Tm (B. ) Tj 1 0 0 1 158.1 324.4 Tm (E. ) Tj 1 0 0 1 170.1 324.4 Tm (Kohler, ) Tj 1 0 0 1 204.4 324.4 Tm (K. ) Tj 1 0 0 1 216.7 324.4 Tm (Song, ) Tj 1 0 0 1 245.5 324.4 Tm ("Lowest ) Tj 1 0 0 1 281.2 324.4 Tm (energy ) Tj 1 0 0 1 312.9 324.4 Tm (excited ) Tj 1 0 0 1 346.8 324.4 Tm (singlet ) Tj 1 0 0 1 376.5 324.4 Tm (states ) Tj 1 0 0 1 405.8 324.4 Tm (of ) Tj 1 0 0 1 416.6 324.4 Tm (isomers ) Tj 1 0 0 1 453.8 324.4 Tm (of ) Tj 1 0 0 1 464.6 324.4 Tm (alkyl) Tj 1 0 0 1 68.4 313.4 Tm (substituted ) Tj 1 0 0 1 122.4 313.4 Tm (hexatrienes," ) Tj 1 0 0 1 185.2 313.4 Tm (J. ) Tj 1 0 0 1 198.7 313.4 Tm (Chern. ) Tj 1 0 0 1 232.0 313.4 Tm (Phys. ) Tj 1 0 0 1 259.4 313.4 Tm (94, ) Tj 1 0 0 1 277.9 313.4 Tm (4691 ) Tj 1 0 0 1 303.6 313.4 Tm (\(1991\).) Tj 1 0 0 1 78.0 302.8 Tm (9. ) Tj 1 0 0 1 89.5 302.8 Tm (H. ) Tj 1 0 0 1 103.9 302.8 Tm (Petek, ) Tj 1 0 0 1 133.2 302.8 Tm (A. ) Tj 1 0 0 1 144.7 302.8 Tm (J. ) Tj 1 0 0 1 156.0 302.8 Tm (Bell, ) Tj 1 0 0 1 178.0 302.8 Tm (R. ) Tj 1 0 0 1 191.0 302.8 Tm (L. ) Tj 1 0 0 1 202.0 302.8 Tm (Christensen, ) Tj 1 0 0 1 259.6 302.8 Tm (and ) Tj 1 0 0 1 278.8 302.8 Tm (K. ) Tj 1 0 0 1 290.1 302.8 Tm (Yoshihara, ) Tj 1 0 0 1 338.8 302.8 Tm ("Dynamical ) Tj 1 0 0 1 389.7 302.8 Tm (Study ) Tj 1 0 0 1 417.8 302.8 Tm (of ) Tj 1 0 0 1 429.1 302.8 Tm (Methyl ) Tj 1 0 0 1 460.3 302.8 Tm (Substituted) Tj 1 0 0 1 68.1 291.8 Tm (Tetraenes ) Tj 1 0 0 1 115.6 291.8 Tm (in ) Tj 1 0 0 1 126.7 291.8 Tm (the ) Tj 1 0 0 1 144.2 291.8 Tm (S1 ) Tj 1 0 0 1 159.1 291.8 Tm (and ) Tj 1 0 0 1 179.0 291.8 Tm (S2 ) Tj 1 0 0 1 194.8 291.8 Tm (Electronically ) Tj 1 0 0 1 255.6 291.8 Tm (Excited ) Tj 1 0 0 1 290.6 291.8 Tm (States," ) Tj 1 0 0 1 327.8 291.8 Tm (\(in ) Tj 1 0 0 1 341.7 291.8 Tm (preparation\).) Tj 1 0 0 1 77.5 280.5 Tm (10. ) Tj 1 0 0 1 93.3 280.5 Tm (M. ) Tj 1 0 0 1 106.8 280.5 Tm (Aoyagi, ) Tj 1 0 0 1 141.6 280.5 Tm (I. ) Tj 1 0 0 1 149.5 280.5 Tm (Ohmine, ) Tj 1 0 0 1 189.3 280.5 Tm (and ) Tj 1 0 0 1 207.6 280.5 Tm (B. ) Tj 1 0 0 1 219.3 280.5 Tm (Kohler, ) Tj 1 0 0 1 252.9 280.5 Tm ("Frequency ) Tj 1 0 0 1 303.6 280.5 Tm (increase ) Tj 1 0 0 1 342.0 280.5 Tm (of ) Tj 1 0 0 1 352.3 280.5 Tm (the ) Tj 1 0 0 1 368.4 280.5 Tm (C ) Tj 1 0 0 1 378.9 280.5 Tm (= ) Tj 1 0 0 1 386.6 280.5 Tm (C ) Tj 1 0 0 1 396.7 280.5 Tm (ag ) Tj 1 0 0 1 409.6 280.5 Tm (stretch ) Tj 1 0 0 1 441.6 280.5 Tm (mode ) Tj 1 0 0 1 468.9 280.5 Tm (of ) Tj 1 0 0 1 479.5 280.5 Tm (polyenes ) Tj 1 0 0 1 520.8 280.5 Tm (in) Tj 1 0 0 1 68.4 267.1 Tm (the ) Tj 1 0 0 1 84.9 267.1 Tm (21 ) Tj 1 0 0 1 95.7 267.1 Tm (AgO ) Tj 1 0 0 1 112.5 267.1 Tm (state: ) Tj 1 0 0 1 141.6 267.1 Tm (Ab ) Tj 1 0 0 1 157.2 267.1 Tm (initio ) Tj 1 0 0 1 180.2 267.1 Tm (MCSCF ) Tj 1 0 0 1 217.6 267.1 Tm (study ) Tj 1 0 0 1 244.5 267.1 Tm (of ) Tj 1 0 0 1 254.6 267.1 Tm (butadiene, ) Tj 1 0 0 1 302.4 267.1 Tm (hexatriene, ) Tj 1 0 0 1 353.0 267.1 Tm (and ) Tj 1 0 0 1 372.2 267.1 Tm (octatetraene," ) Tj 1 0 0 1 431.5 267.1 Tm (J. ) Tj 1 0 0 1 442.5 267.1 Tm (Phys. ) Tj 1 0 0 1 470.4 267.1 Tm (Chern ) Tj 1 0 0 1 498.9 267.1 Tm (94,) Tj 1 0 0 1 69.1 255.6 Tm (3922 ) Tj 1 0 0 1 101.0 255.6 Tm (\(1990\).) Tj 1 0 0 1 78.4 244.8 Tm (11. ) Tj 1 0 0 1 94.8 244.8 Tm (M. ) Tj 1 0 0 1 108.7 244.8 Tm (F. ) Tj 1 0 0 1 120.2 244.8 Tm (Granville, ) Tj 1 0 0 1 163.9 244.8 Tm (G. ) Tj 1 0 0 1 177.6 244.8 Tm (R. ) Tj 1 0 0 1 190.5 244.8 Tm (Holtom. ) Tj 1 0 0 1 226.5 244.8 Tm (B. ) Tj 1 0 0 1 239.0 244.8 Tm (E. ) Tj 1 0 0 1 251.0 244.8 Tm (Kohler, ) Tj 1 0 0 1 285.1 244.8 Tm ("High ) Tj 1 0 0 1 310.8 244.8 Tm (resolution ) Tj 1 0 0 1 354.4 244.8 Tm (one ) Tj 1 0 0 1 374.1 244.8 Tm (and ) Tj 1 0 0 1 392.8 244.8 Tm (two ) Tj 1 0 0 1 411.1 244.8 Tm (photon ) Tj 1 0 0 1 443.5 244.8 Tm (excitation ) Tj 1 0 0 1 487.4 244.8 Tm (spectra ) Tj 1 0 0 1 522.4 244.8 Tm (of) Tj 1 0 0 1 69.8 233.2 Tm (trans, ) Tj 1 0 0 1 100.3 233.2 Tm (trans-1,3,5,7-octatetraene," ) Tj 1 0 0 1 232.8 233.2 Tm (J. ) Tj 1 0 0 1 246.2 233.2 Tm (Chern. ) Tj 1 0 0 1 280.3 233.2 Tm (P'hys. ) Tj 1 0 0 1 308.6 233.2 Tm (72, ) Tj 1 0 0 1 327.6 233.2 Tm (4671 ) Tj 1 0 0 1 354.9 233.2 Tm (\(1980\).) Tj 1 0 0 1 79.4 223.2 Tm (12. ) Tj 1 0 0 1 95.5 223.2 Tm (H. ) Tj 1 0 0 1 108.2 223.2 Tm (Yoshida, ) Tj 1 0 0 1 149.5 223.2 Tm (Y. ) Tj 1 0 0 1 161.7 223.2 Tm (Furukawa, ) Tj 1 0 0 1 210.2 223.2 Tm (and ) Tj 1 0 0 1 228.9 223.2 Tm (M. ) Tj 1 0 0 1 242.6 223.2 Tm (Tasumi, ) Tj 1 0 0 1 280.5 223.2 Tm ("Structural ) Tj 1 0 0 1 327.6 223.2 Tm (studies ) Tj 1 0 0 1 361.2 223.2 Tm (and ) Tj 1 0 0 1 379.9 223.2 Tm (vibrational ) Tj 1 0 0 1 427.2 223.2 Tm (analysis ) Tj 1 0 0 1 465.8 223.2 Tm (of ) Tj 1 0 0 1 477.1 223.2 Tm (stable ) Tj 1 0 0 1 506.1 223.2 Tm (and) Tj 1 0 0 1 69.6 212.1 Tm (less ) Tj 1 0 0 1 90.4 212.1 Tm (stable ) Tj 1 0 0 1 121.2 212.1 Tm (conformers ) Tj 1 0 0 1 174.9 212.1 Tm (of ) Tj 1 0 0 1 187.6 212.1 Tm (1,3,5-hexatriene ) Tj 1 0 0 1 262.0 212.1 Tm (based ) Tj 1 0 0 1 292.8 212.1 Tm (on ) Tj 1 0 0 1 308.1 212.1 Tm (ab ) Tj 1 0 0 1 323.0 212.1 Tm (initio ) Tj 1 0 0 1 347.0 212.1 Tm (calculations." ) Tj 1 0 0 1 408.4 212.1 Tm (J. ) Tj 1 0 0 1 420.4 212.1 Tm (Mol. ) Tj 1 0 0 1 442.8 212.1 Tm (Struct. ) Tj 1 0 0 1 475.4 212.1 Tm (194, ) Tj 1 0 0 1 499.4 212.1 Tm (279) Tj 1 0 0 1 68.1 199.4 Tm (\(1989\).) Tj 1 0 0 1 79.4 188.4 Tm (13. ) Tj 1 0 0 1 96.2 188.4 Tm (B. ) Tj 1 0 0 1 109.2 188.4 Tm (E. ) Tj 1 0 0 1 121.6 188.4 Tm (Kohler, ) Tj 1 0 0 1 156.0 188.4 Tm (P. ) Tj 1 0 0 1 168.4 188.4 Tm (Mitra, ) Tj 1 0 0 1 196.8 188.4 Tm (and ) Tj 1 0 0 1 216.0 188.4 Tm (P. ) Tj 1 0 0 1 228.7 188.4 Tm (West, ) Tj 1 0 0 1 257.2 188.4 Tm ("Barriers ) Tj 1 0 0 1 297.6 188.4 Tm (in ) Tj 1 0 0 1 308.1 188.4 Tm (the ) Tj 1 0 0 1 325.2 188.4 Tm (excited ) Tj 1 0 0 1 358.5 188.4 Tm (21Ag ) Tj 1 0 0 1 384.0 188.4 Tm (state ) Tj 1 0 0 1 408.4 188.4 Tm (of ) Tj 1 0 0 1 420.4 188.4 Tm (cis, ) Tj 1 0 0 1 439.2 188.4 Tm (trans-octatetraene:) Tj 1 0 0 1 68.6 176.6 Tm (General ) Tj 1 0 0 1 107.0 176.6 Tm (features ) Tj 1 0 0 1 146.4 176.6 Tm (and ) Tj 1 0 0 1 166.3 176.6 Tm (the ) Tj 1 0 0 1 184.0 176.6 Tm (excited ) Tj 1 0 0 1 218.8 176.6 Tm (state ) Tj 1 0 0 1 244.0 176.6 Tm (potential," ) Tj 1 0 0 1 290.6 176.6 Tm (J. ) Tj 1 0 0 1 302.8 176.6 Tm (Chern. ) Tj 1 0 0 1 334.8 176.6 Tm (Phys. ) Tj 1 0 0 1 360.2 176.6 Tm (85, ) Tj 1 0 0 1 379.9 176.6 Tm (4436 ) Tj 1 0 0 1 404.1 176.6 Tm (\(1986\).) Tj 1 0 0 1 80.1 166.3 Tm (14 ) Tj 1 0 0 1 95.5 166.3 Tm (D. ) Tj 1 0 0 1 108.2 166.3 Tm (G. ) Tj 1 0 0 1 123.1 166.3 Tm (Leopold, ) Tj 1 0 0 1 161.2 166.3 Tm (V. ) Tj 1 0 0 1 174.9 166.3 Tm (Vaida, ) Tj 1 0 0 1 204.7 166.3 Tm (and ) Tj 1 0 0 1 223.2 166.3 Tm (M. ) Tj 1 0 0 1 237.3 166.3 Tm (F. ) Tj 1 0 0 1 248.6 166.3 Tm (Granville, ) Tj 1 0 0 1 293.2 166.3 Tm ("Direct ) Tj 1 0 0 1 323.7 166.3 Tm (absorption ) Tj 1 0 0 1 370.8 166.3 Tm (spectroscopy ) Tj 1 0 0 1 430.3 166.3 Tm (of ) Tj 1 0 0 1 440.4 166.3 Tm (jet-cooled ) Tj 1 0 0 1 485.0 166.3 Tm (polyenes.) Tj 1 0 0 1 68.4 156.2 Tm (I. ) Tj 1 0 0 1 81.1 156.2 Tm (The ) Tj 1 0 0 1 101.7 156.2 Tm (1 ) Tj 1 0 0 1 106.5 156.2 Tm (Bu+ ) Tj 1 0 0 1 128.1 156.2 Tm (t- ) Tj 1 0 0 1 140.1 156.2 Tm (1 ) Tj 1 0 0 1 145.4 156.2 Tm (Ag- ) Tj 1 0 0 1 163.9 156.2 Tm (transition ) Tj 1 0 0 1 208.0 156.2 Tm (of ) Tj 1 0 0 1 221.0 156.2 Tm (trans, ) Tj 1 0 0 1 250.3 156.2 Tm (trans-octatetraene," ) Tj 1 0 0 1 341.0 156.2 Tm (J. ) Tj 1 0 0 1 354.7 156.2 Tm (Chern. ) Tj 1 0 0 1 387.1 156.2 Tm (Phys. ) Tj 1 0 0 1 414.7 156.2 Tm (81, ) Tj 1 0 0 1 432.9 156.2 Tm (4210 ) Tj 1 0 0 1 458.8 156.2 Tm (\(1984\).) 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